WebMar 31, 2024 · The first metal-catalyzed oxidative alkynylations of primary alcohols or aldehydes to form α,β-acetylenic ketones (ynones) are described. Deuterium labeling studies corroborate a novel reaction mechanism in which alkyne hydroruthenation forms a transient vinylruthenium complex that deprotonates the terminal alkyne to form the active … WebD.R. Evarts Library Contact: Janet Dymond 80 Second Street Athens, NY 12015 Phone: (518) 945-1417 Fax: (518) 9451725 Email: [email protected] Website: drevartslibrary.org. Palenville Branch Library; 3303 Route 23A Palenville, NY 12463 Phone: (518) 678-3357 Fax: (518) 678-9251
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